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Kinetic Particle Theorey | Chemistry
- Kinetic Particle Theory
- What
is Kinetic Particle Theory The kinetic particle theory states that all
matter is made up of tiny particles and that these particles are in
constant, random motion.
- Uses
of the Kinetic Particle Theory • Describes the states of matter • Explains
the differences in the properties of solids, liquids and gases • Explains
the changes of states
- Three
States of Matter ICE WATER STEAM Solid Liquid Gas
- Particles
and properties
- Properties
of Solid, Liquid & Gas Properties Solid Liquid Gas Sample picture of
how the particles are arranged Shape Volume Compressibility Fixed Fixed
Fixed Not fixed Not fixed Not fixed Cannot be compressed Cannot be
compressed Can be compressed
- How
do particles move?
- Properties
Solid Liquid Gas Motion of molecules Arrangement of molecules
Intermolecular forces Distance between molecules Energy of the particles
Vibrations about fixed position only Arranged in fixed and orderly
arrangement Slide past & movement through liquid No fixed arrangement
Vibrations and movement anywhere No fixed arrangement Very strong Weak
Negligible Packed very close together Not so closely packed Very far apart
According to Kinetic Particle Theory Less energy than liquids or gases
More energy than solids but less than gases More energy than solids or
liquids
- Properties
Solid Liquid Gas Shape Reason: Reason: Reason: Volume Reason: Reason:
Reason: Compressibility Reason: Reason: Reason: Fixed Fixed Fixed Not
fixed Not fixed Not fixed Cannot be compressed Cannot be compressed Can be
compressed • Particles are held together by strong forces of attraction. •
Vibrate about fixed positions & cannot move about freely. • Particles
are held together by weaker attractive forces • Not held in fixed
positions • Move freely by sliding over one another • Forces of attraction
between particles are very weak • Not held in fixed positions • Move
rapidly in any direction • Particles are packed very close to one another
• Particles are packed very close to one another • Almost no empty spaces
between particles • Particles are further away from one another •
Particles are still packed quite closely together • Particles are further
away from one another • Particles are still packed quite closely together
• Large space between particles • Can be forced to move closer together •
Large space between particles • Can be forced to move closer together
Relating Properties of Solid, Liquid & Gas to the Kinetic Particle
Theory
- Cornflour
paste: solid or liquid?
- Multiple-choice
quiz
- . Changes
of State Is it reversible?
- SOLID
LIQUID GAS 1. M ELTING Changes of State
- Melting What happens to the particles of a solid that is heated until it
melts? As heat energy is supplied to the solid and converted into kinetic
energy, the particles vibrate faster about their fixed positions. When the
vibrations of the particles overcome the attractive forces between them,
they begin to break away from their fixed positions. The particles slide
over one another and the substance is now a liquid. Heat energy
- Heating
Curve (Melting) Temperature/o C Time/min A à
B: Solid heats up. The temperature of the solid increases until it reaches
point B, its melting point. At point B, the solid begins to melt. B à
C: Solid melts. A mixture of solid and liquid exists here. During the
melting process, the temperature of the substance remains constant even
though heating continues. All the heat energy taken in by the particles is
used to overcome the forces of attraction between particles. C à
D: Liquid heats up. At point C, all the solid has melted and the
temperature of the liquid rises as heating continues.
- SOLID
LIQUID GAS 2. FREEZING 1. Melting Changes of State
- .
Freezing Energy is given out by the particles of the liquid. They lose
kinetic energy and begin to move more slowly. When the temperature is low
enough, the particles do not have enough energy to move freely. Some
particles start to settle into fixed positions. Finally, all the particles
settle into fixed positions. Particles can only vibrate about their fixed
positions. The substance is now a solid. What happens to the particles of
a liquid that is cooled until it freezes?
- Cooling
Curve (Freezing) Temperature/o C Time/min P – Q: Liquid cools. The
temperature of the liquid drops until it reaches point Q, the freezing
point of naphthalene. At point Q, the liquid starts to freeze. Q – R:
liquid freezes. A mixture of liquid and solid exists here. During the
freezing process, the temperature of the substance remains constant even
though cooling continues. R – S: solid cools. At point R, the substance
has solidified. The temperature of the solid continues to drop as it is
cooled.
- SOLID
LIQUID GAS 3. Evaporation / Boiling 2. Freezing 1. Melting Changes of
State
- Boiling As the liquid is heated, the particles gain kinetic energy and
start to move faster. Eventually, the particles have enough energy to
overcome the attractive forces holding them together. They spread far
apart and move rapidly in all directions. The substance is now a gas.
- Heating
Curve (Boiling) Temperature/o C Time/min When a liquid is heated, its
temperature increases till its boiling point is reached. Here, it boils
and changes into a vapour. Temperature remains constant till all the
liquid has boiled off. Heat energy taken in is used to overcome forces of
attraction between the particles of the liquid and to make the particles
move further apart. X Y The temperature remains constant till all the
liquid has boiled off Z
- SOLID
LIQUID GAS 3. Evaporation / Boiling 2. Freezing 1. Melting Changes of
State
- Evaporation Evaporation occurs because some particles have enough energy
(more kinetic energy) to escape as a gas from the surface of the liquid.
Volatile liquids are liquids that evaporate quickly at room temperature.
E.g. Petrol and perfumes.
- Differences
between Evaporation & Boiling Evaporation Boiling • Occurs at
temperatures below boiling point • Occurs only at the surface of the
liquid • Occurs slowly • Occurs only at boiling point • Occurs throughout
the liquid • Occurs rapidly
- SOLID
LIQUID GAS 4. Condensation 3. Evaporation / Boiling 2. Freezing 1. Melting
4. Sublimation Changes of State
- Condensation • Condensation occurs when a gas is cooled sufficiently to
change into a liquid.
- Eventually,
the movement of the particles becomes slow enough for the gas to change
into a liquid / move closer to slide past one another. Heat energy is
given out, and the gas particles lose energy and move more slowly as the
temperature drops. 4. Condensation
- SOLID
LIQUID GAS 4. Condensation 3. Evaporation / Boiling 2. Freezing 1. Melting
4. Sublimation 5. Condensation Changes of State
- Sublimation Dry ice sublimes • Sublimation involves changing solids
directly into a gas without going through the liquid state. • Examples of
substances undergoing sublimation: 1. Dry ice (Solid carbon dioxide) 2.
Solid Iodine 3. Ammonium Chloride 4. Naphthalene (Moth ball)
- Sublimation • Occurs because particle at the surface have enough energy to
break off from the solid and become gas SOLID GAS Solid iodine Iodine
vapour A substance sublimes because the forces between the particles in
the liquid state are too weak to remain in this state.
- Summary
Mixture of Solid & Liquid Mixture of Liquid & Gas SOLID LIQUID GAS
MELTING POINT BOILING POINT
- Summary
Heat Absorbed (endothermic) Heat given out (Exothermic) Process involved
Melting Boiling Evaporation Sublimation Freezing Condensation
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